Advanced Energy Materials
26 April 2024
Upgrading Cycling Stability and Capability of Hybrid Na-CO2 Batteries via Tailoring Reaction Environment for Efficient Conversion CO2 to HCOOH
Xiecheng Yang1,2,†, Dantong Zhang3,†, Lanqing Zhao1,2, Chao Peng3, Kun Ren1,2, Changfan Xu4, Pan Liu1,2, Yingjie Zhou1,2, Yong Lei4, Bin Yang1,2, Dongfeng Xue5, and Feng Liang1,2,6,*
1 Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093 China
2 National Engineering Research Center of Vacuum Metallurgy, Kunming University of Science and Technology, Kunming, 650093 China
3 Multiscale Crystal Materials Research Center, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
4 Fachgebiet Angewandte Nanophysik, Institut für Physik & IMNMacroNano, Technische Universität Ilmenau, 98693 Ilmenau, Germany
5 Shenzhen Institute for Advanced Study, University of Electronic Science and Technology of China, Shenzhen, 518110 China
6 Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, Kunming University of Science and Technology, Kunming, 650093 China
† X.Y. and D.Z. contributed equally to this work.
10.1002/aenm.202304365
In the article number 2304365, Feng Liang and co-workers controlled the relative concentration of H/O atoms at the catalyst/electrolyte interface by designing the electrolyte and establishing a reaction environment conducive to the generation of HCOOH. The hybrid Na-CO2 battery, based on the discharge product of HCOOH, exhibits an ultra-high discharge specific capacity and excellent cycle reversibility, especially low-temperature cycle stability.
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